Lithium bromide

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Lithium bromide
Properties
Molecular formula LiBr
Molar mass 86.845 g/mol
Appearance White crystalline powder
Density 3.464 g/cm3, Solid
Melting point

552 °C

Boiling point

1265 °C

Solubility in water 177 g/100 ml (20°C) (dihydrate)
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

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Overview

Lithium bromide, or LiBr, is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.[1]

Production and properties

LiBr is prepared by treatment of lithium carbonate with hydrobromic acid. The salt forms several crystalline hydrates, unlike the other alkali metal bromides.[1] The anhydrous salt forms cubic crystals similar to salt

Uses

Lithium bromide is used in air-conditioning systems as desiccant. Otherwise the salt is useful as a reagent in organic synthesis. For example it reversibly forms adducts with some pharmaceuticals.[1]

Medical applications

Lithium bromide was used as a sedative beginning in the early 1900s, but it fell into disfavor in the 1940s when some heart patients died after using it as a salt substitute.[1] Like lithium carbonate and lithium chloride it was used as treatment for Bipolar disorder.

Hazards

Lithium salts are psychoactive and somewhat corrosive. Dosages for lithium carbonate are ca. 200 mg/day.

References


External links

bs:Litijum bromid ca:Bromur de liti de:Lithiumbromid it:Bromuro di litio

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Acknowledgement and Attribution Regarding Sources of Content

Some of the initial content on this page may be incorporated in part from copyleft sources in the public domain including wikis such as Wikipedia and AskDrWiki. Drug information for patients came from the The National Library of Medicine. Infectious disease information may have come from the Centers for Disease Control (CDC). Differential Diagnoses are drawn from clinicians as well as an amalgamation of 3 sources: 1.The Disease Database; 2. Kahan, Scott, Smith, Ellen G. In A Page: Signs and Symptoms. Malden, Massachusetts: Blackwell Publishing, 2004:3; 3. Sailer, Christian, Wasner, Susanne. Differential Diagnosis Pocket. Hermosa Beach, CA: Borm Bruckmeir Publishing LLC, 2002:7 .

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