Sodium fluoride

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Sodium fluoride
IUPAC name Sodium fluoride
Identifiers
CAS number 7681-49-4
Properties
Molecular formula NaF
Molar mass 41.99 g/mol
Appearance White solid
Density 2.558 g/cm³, solid
Melting point

993 °C

Boiling point

1700 °C

Solubility in water 4.13 g/100 g at 25 °C
Hazards
EU classification Toxic (T)
NFPA 704

0
2
0
 
R-phrases R25, R32,
R36, R38
S-phrases S22, S36, S45
Flash point Non-flammable.
Related Compounds
Other anions sodium chloride
sodium bromide
sodium iodide
Other cations potassium fluoride
calcium fluoride
caesium fluoride
Related bases None listed.
Related compounds TASF reagent
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

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Sodium fluoride is an ionic compound with the formula NaF. This colourless solid is the main source of the fluoride ion in diverse applications. NaF is less expensive and less hygroscopic than KF, but otherwise the potassium salt is more widely used.

Chemical structure and properties

NaF crystallizes in the sodium chloride motif where both Na+ and F occupy octahedral coordination sites.[1]

It is usually used as a reagent for the synthesis of fluorides. Representative substrates include electrophilic chlorides including acyl chlorides, sulfur chlorides, and phosphorus chloride.[1] Like other fluorides, NaF finds use in desilylation in organic synthesis.

Uses

Sodium fluoride is sold in tablets for cavity prevention.
Sodium fluoride is sold in tablets for cavity prevention.

Fluoride salts are used widely to enhance the strength of teeth by the formation of fluoroapatite, a naturally occurring component of tooth enamel. In the US, NaF was once used to fluoridate drinking water but its use has been displaced by hexafluorosilicic acid (H2SiF6) or its sodium salt (Na2SiF6). Toothpaste often contains sodium fluoride to prevent cavities.

Sodium fluoride was also used as an antibiotic, as rat poison, and in ceramics.


See also

References


External links

de:Natriumfluorid

it:Fluoruro di sodio hu:Nátrium-fluorid nl:Natriumfluoride ja:フッ化ナトリウムfi:Natriumfluoridi

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Acknowledgement and Attribution Regarding Sources of Content

Some of the initial content on this page may be incorporated in part from copyleft sources in the public domain including wikis such as Wikipedia and AskDrWiki. Drug information for patients came from the The National Library of Medicine. Infectious disease information may have come from the Centers for Disease Control (CDC). Differential Diagnoses are drawn from clinicians as well as an amalgamation of 3 sources: 1.The Disease Database; 2. Kahan, Scott, Smith, Ellen G. In A Page: Signs and Symptoms. Malden, Massachusetts: Blackwell Publishing, 2004:3; 3. Sailer, Christian, Wasner, Susanne. Differential Diagnosis Pocket. Hermosa Beach, CA: Borm Bruckmeir Publishing LLC, 2002:7 .

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